Issue 7, 1992
From the journal:

Journal of the Chemical Society, Chemical Communications

A d4-thiolato–dinitrogen complex. The synthesis and crystal structure of [Re(N2)(SC6H2-2,4,6-Pri3)3(PPh3)]

Jonathan R. Dilworth,   Jin Hu,   Russell M. Thompson  and  David L. Hughes  

Abstract

[ReH7(PPh3)2] or [ReH5(PPh3)3] reacted with L [L = 2,4,6-triisopropylthiophenol (Htipt) or HSC6h2-2,6-Pri2,4-Br (Hdipbt)] in toluene, under dinitrogen, to give [Re(N2)(tipt)3(PPh3)] and [Re(N2)(dipbt)3(PPh3)], respectively in good yield, and under similar conditions 2,6-dimethyithiophenol (Hdmt) or 2,6-dimethoxythiophenol (Hdmot) gave [Re(dmt)3(PPh3)] and [Re(dmot)3(PPh3)] respectively; the complex [Re(dmt)3(PPh3)(PPh2H)] was also isolated from the same reaction with Hdmt.

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Article information

DOI
https://doi.org/10.1039/C39920000551
Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 551-553

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A d4-thiolato–dinitrogen complex. The synthesis and crystal structure of [Re(N2)(SC6H2-2,4,6-Pri3)3(PPh3)]

J. R. Dilworth, J. Hu, R. M. Thompson and D. L. Hughes, J. Chem. Soc., Chem. Commun., 1992, 551 DOI: 10.1039/C39920000551

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