Issue 6, 1992
From the journal:

Journal of the Chemical Society, Chemical Communications

First delocalization of a mono-fulvalene-bridged mixed-valence diiron complex on the infrared time scale

Marie-Hélène Delville,   Stefan Rittinger  and  Didier Astruc  

Abstract

Measurement of the infrared νCH(Cp) stretch around 800 cm–1 of the FeIIFeII(q= 2), FeII FeI(q= 1) and FeIFeI(q= 0) states of [Fe2Fv(C6Me6)2]q+(Fv= fulvalene) and FeIIFeII(q= 0), FeIIFeIII(q= 1) and FeIIIFeIII(q= 2) states of [Fe2Fv(C5Me5)2]q+ shows that FeIIFeI is delocalized whereas FeIIFeIII is localized; the electrochemical E° values indicate that the cyclopentadienyl permethylation increases the delocalization in the arene series whereas it decreases it in the C5Me5 one.

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Article information

DOI
https://doi.org/10.1039/C39920000519
Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 519-520

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First delocalization of a mono-fulvalene-bridged mixed-valence diiron complex on the infrared time scale

M. Delville, S. Rittinger and D. Astruc, J. Chem. Soc., Chem. Commun., 1992, 519 DOI: 10.1039/C39920000519

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