Issue 6, 1992

Asymmetric functionalisation of prochiral 1,3-diols based on an efficient 1,6-chiral induction: the diastereoselective C–O bond fission in chiral β-arylsulfinyl acetal via two types of chelation control

Abstract

The novel asymmetric functionalisation of a prochiral 1,3-diol is accomplished by the diastereoselective C–O bond fission of the chiral β-arylsulfinyl acetal via two types of chelation controlled transition states (A and C in Scheme 4).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 516-518

Asymmetric functionalisation of prochiral 1,3-diols based on an efficient 1,6-chiral induction: the diastereoselective C–O bond fission in chiral β-arylsulfinyl acetal via two types of chelation control

C. Iwata, N. Maezaki, M. Murakami, M. Soejima, T. Tanaka and T. Imanishi, J. Chem. Soc., Chem. Commun., 1992, 516 DOI: 10.1039/C39920000516

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