The novel asymmetric functionalisation of a prochiral 1,3-diol is accomplished by the diastereoselective C–O bond fission of the chiral β-arylsulfinyl acetal via two types of chelation controlled transition states (A and C in Scheme 4).
C. Iwata, N. Maezaki, M. Murakami, M. Soejima, T. Tanaka and T. Imanishi, J. Chem. Soc., Chem. Commun., 1992, 516 DOI: 10.1039/C39920000516
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