Kinetic studies on the reaction between [WH4(PMePh2)4] and anhydrous HCl in tetrahydrofuran show that the formation of [WH5(PMePh2)4]+ occurs by two pathways, one involving direct protonation at the metal and the other involving initial attack at a hydrido ligand to generate [WH3(η2-H2)(PMePh2)4]+ which subsequently rearranges to give the pentahydride.
K. E. Oglieve and R. A. Henderson, J. Chem. Soc., Chem. Commun., 1992, 441 DOI: 10.1039/C39920000441
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