Issue 5, 1992

The kinetics of pyrolysis of 1,3,3-trimethylcyclopropene. Evidence for the involvement of alkylidene carbenes in the thermal isomerisation of cyclopropenes

Abstract

A low yield of 4-methylpent-2-yne in the gas-phase isomerisation of 1,3,3-trimethylcyclopropene is shown to be more consistent with an alkylidene carbene transient than with a, 1,3-biradical intermediate.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 421-422

The kinetics of pyrolysis of 1,3,3-trimethylcyclopropene. Evidence for the involvement of alkylidene carbenes in the thermal isomerisation of cyclopropenes

R. Walsh, C. Wolf, S. Untiedt and A. de Meijere, J. Chem. Soc., Chem. Commun., 1992, 421 DOI: 10.1039/C39920000421

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