Intermolecular magnetic interactions in a mixed-valence compound: inelastic neutron scattering spectrum of [FeIII2FeIIO(O2CCD3)6(C5D5N)3](C5D5N)
Abstract
An inelastic neutron scattering spectrum of the mixed-valence compound [FeIII2FeIIO(O2CCD3)6(C5D5N)3](C5D5N) shows 11 energy transfers in the frequency range 2–25 cm–1, which disappear on dilution in a host lattice, indicating intermolecular origin; this is the first evidence of strong intermolecular electronic interactions in a mixed-valence system.
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