Chiral catalytic cavities were imprinted on a silica gel surface using a chiral template, N-benzoyl-(Nα-benzyloxycarbonyl)-L- alanineamide, by an imprinting procedure; these cavities display enatioselective catalysis in 2,4-dinitrophenolysis of the corresponding substrate, benzoic N-benzyloxycarbonyl-L-alanine anhydride.
K. Morihara, M. Kurokawa, Y. Kamata and T. Shimada, J. Chem. Soc., Chem. Commun., 1992, 358 DOI: 10.1039/C39920000358
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