Issue 3, 1992
From the journal:

Journal of the Chemical Society, Chemical Communications

Lossen-like rearrangement of N-[α-methylbenzyl(phenyl)phosphinoyl]-O-methylsulfonylhydroxylamine with methylamine: retention of configuration at phosphorus as revealed by X-ray crystallography

John Fawcett,   Martin J. P. Harger  and  Ramesh Sreedharan Menon  

Abstract

The diastereoisomers of the title compound 6 rearrange with high stereospecificity on treatment with MeNH2, giving PhMeCHP(O)(NHMe)NHPh in which the migrating phenyl group has been replaced by MeNH2 with retention of configuration at phosphorus.

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Article information

DOI
https://doi.org/10.1039/C39920000227
Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 227-229

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Lossen-like rearrangement of N-[α-methylbenzyl(phenyl)phosphinoyl]-O-methylsulfonylhydroxylamine with methylamine: retention of configuration at phosphorus as revealed by X-ray crystallography

J. Fawcett, M. J. P. Harger and R. S. Menon, J. Chem. Soc., Chem. Commun., 1992, 227 DOI: 10.1039/C39920000227

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