The treatment of two protected β-D-glycosyl azides by N-bromosuccinimide in refluxing carbon tetrachloride under free-radical conditions leads to efficient preparations of the corresponding bromoimino derivatives via an unprecedented reaction of organic azides leading, in the present case, to new sugar derivatives.
J. Praly, C. Di Stéfano, L. Somsák and G. Descotes, J. Chem. Soc., Chem. Commun., 1992, 200 DOI: 10.1039/C39920000200
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