High temperature reaction of niobium, NbOl3, tellurium and iodine produces [Te4Nb3O(Te2)2I6]I 1, which contains one square planar Te4 ring and two Te2 groups coordinated to a trinuclear metal cluster.
W. Tremel, J. Chem. Soc., Chem. Commun., 1992, 126 DOI: 10.1039/C39920000126
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