Free radicals and carbocations are generated competitively in nitrous acid deamination reactions of α-aminonitriles; in the absence of addedd scavengers the radicals are trapped by NO2 and by NO.
M. Bunse, D. Jödicke and W. Kirmse, J. Chem. Soc., Chem. Commun., 1992, 47 DOI: 10.1039/C39920000047
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