Issue 1, 1992

Synthesis of allenylketenimines via titanocene vinylidene complexes

Abstract

The intermolecular addition of in situ generated titanocene vinylidene complexes to alkynes gives titanacyclobutenes which undergo an insertion–rearrangement with tert-butyl isocyanide to afford allenylketenimines in high yield.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 35-36

Synthesis of allenylketenimines via titanocene vinylidene complexes

R. D. Dennehy and R. J. Whitby, J. Chem. Soc., Chem. Commun., 1992, 35 DOI: 10.1039/C39920000035

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