Addition of Me2S2 to Ru5(µ5-C2PPh2)(µ-PPh2)(CO)131 resulted in a sequence of Ru–Ru bond cleavage and formation reactions; the structures of two of the products, Ru5(µ-C2)(µ-SMe)2(µ-PPh2)2(CO)123 and Ru5(µ5-C2)(µ-SMe)2(µ-PPh2)2(CO)114, which contain dicarbon (C2) attached to open and closed Ru5 pentagons, respectively, are described.
C. J. Adams, M. I. Bruce, B. W. Skelton and A. H. White, J. Chem. Soc., Chem. Commun., 1992, 26 DOI: 10.1039/C39920000026
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