Issue 3, 1992

Nucleophilic substitution reactions of spin adducts. Implications for the correct identification of reaction intermediates by EPR/spin trapping

Abstract

Radical adducts to nitrone spin traps have been shown, in aqueous solution, to undergo conversion to the hydroxyl radical adduct via nucleophilic substitution reactions; these observations have important consequences for the interpretation of data from EPR/spin-trapping experiments.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1992, 333-335

Nucleophilic substitution reactions of spin adducts. Implications for the correct identification of reaction intermediates by EPR/spin trapping

M. J. Davies, B. C. Gilbert, J. K. Stell and A. C. Whitwood, J. Chem. Soc., Perkin Trans. 2, 1992, 333 DOI: 10.1039/P29920000333

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