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Issue 16, 1992
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Dalton communications. A convenient high-yield synthesis of some titanium(IV) oxo cluster compounds: crystal structure of [Ti3Cl3(µ-O2CC6H4Me-p)5(µ-O)(µ3-O)]

Abstract

The reaction of TiCl4 with a series of para-substituted benzoic acids (p-XC6H4CO2H; X = Me, Et, F or I) yields the new trinuclear oxo clusters [Ti3Cl3(µ-O2CC6H4X-p)5(µ-O)(µ3-O)] in good yield; p-ButC6H4CO2H gives [{[TiCl(O2CR)2]2O}n] but p-MeOC6H4CO2H yields only a black intractable tar.

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Article type: Paper
DOI: 10.1039/DT9920002529
J. Chem. Soc., Dalton Trans., 1992, 2529-2530

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    Dalton communications. A convenient high-yield synthesis of some titanium(IV) oxo cluster compounds: crystal structure of [Ti3Cl3(µ-O2CC6H4Me-p)5(µ-O)(µ3-O)]

    A. Bashall, D. A. Brown, M. McPartlin and M. G. H. Wallbridge, J. Chem. Soc., Dalton Trans., 1992, 2529
    DOI: 10.1039/DT9920002529

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