Product ion studies indicate that the collision-induced loss of N2 from deprotonated aryl diazomethyl ketones yields an ion formed by Wolff rearrangement, e.g. PhCO [graphic omitted]→N2+ Ph[graphic omitted] → PhC2O–
A. T. Lebedev, R. N. Hayes and J. H. Bowie, J. Chem. Soc., Perkin Trans. 2, 1991, 1127 DOI: 10.1039/P29910001127
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