Electron ionization of sulphur-containing Nuphar alkaloids leads to the formation of easily detectable, doubly-charged species. The study of charge-separation reactions by collision experiments allows us to determine the intercharge distances. These experimental figures agree well with the different stereochemistries of the compounds under investigation.
O. Bortolini, O. Curcuruto, P. Traldi, A. Iwanow and J. T. Wróbel, J. Chem. Soc., Perkin Trans. 2, 1991, 287 DOI: 10.1039/P29910000287
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