N-Boryl imines obtained from partial reduction of nitriles with borane–tetrahydrofuran have been alkylated with organolithium or Grignard reagents to afford secondary carbinamines in moderate to excellent yields.
S. Itsuno, C. Hachisuka and K. Ito, J. Chem. Soc., Perkin Trans. 1, 1991, 1767 DOI: 10.1039/P19910001767
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