SCHEDULED MAINTENANCE
A common intermediate, presumably phthalimidonitrene 1, is generated in the thermolysis of the aziridinobenzofurans 3(R = Ac, CO2Me, Bz, COBut and CN) as well as the sulphimide 4, and the azabenzonorbornadiene 5. The transfer of 1 shown in Scheme 1 is zero order in 2-acetylbenzofuran providing further evidence against a concerted bimolecular mechanism 10 for ‘nitrene’ transfer.
R. S. Atkinson, D. W. Jones and B. J. Kelly, J. Chem. Soc., Perkin Trans. 1, 1991, 1344 DOI: 10.1039/P19910001344
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