N-(Trimethylsilyl)benzaldehyde imine was alkylated with chirally modified organometallic reagents to give optically active primary amines in moderate to good yields with an enantiomeric excess (e.e.) of up to 62%.
S. Itsuno, H. Yanaka, C. Hachisuka and K. Ito, J. Chem. Soc., Perkin Trans. 1, 1991, 1341 DOI: 10.1039/P19910001341
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