trans-1,3-Dithiane 1,3-dioxide, prepared by stereoselective oxidation of 1,3-dithiane has been found to be thermodynamically more stable than the cis-isomer by equilibration studies using N2O4 and has been found to undergo highly selective (20 : 1) aldol type reactions with benzaldehyde.
V. K. Aggarwal, I. W. Davies, R. J. Franklin, J. Maddock, M. F. Mahon and K. C. Molloy, J. Chem. Soc., Perkin Trans. 1, 1991, 662 DOI: 10.1039/P19910000662
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