Issue 2, 1991

Synthesis of α-substituted allyl- and homoallyl-stannanes by selenoxide elimination

Abstract

The α-methyl-, α-phenyl- and α,α-dimethyl-allylstannanes 20–22 have been prepared by oxidative elimination of the corresponding primary selenides 17–19, and were found to be stable with respect to 1,3-migration of the tributyltin moiety in non-polar solvents (t⩽ 100 °C). Homoallylstannanes 32–34 were the major products obtained by oxidative elimination of the secondary selenides 29–31, with mixtures of regioisomers being obtained from the other secondary selenides investigated.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1991, 429-434

Synthesis of α-substituted allyl- and homoallyl-stannanes by selenoxide elimination

V. J. Jephcote and E. J. Thomas, J. Chem. Soc., Perkin Trans. 1, 1991, 429 DOI: 10.1039/P19910000429

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