Issue 1, 1991
From the journal:

Journal of Materials Chemistry

Thermal and electrical conduction studies on polypyrrole tetracyanoplatinate

Stephen Edge,   Allan E. Underhill,   Poopathy Kathirgamanathan,   Patrick O'Connor  and  Andrew J. Dent  

Abstract

Polypyrrole tetracyanoplatinate [PPPt(CN)4] has been prepared by the electrochemical polymerisation of pyrrole in aqueous K2Pt(CN)4. The polymer behaved as a semiconductor with a room-temperature conductivity of 17 S cm–1 and an activation energy of 9 meV between 270 and 110 K.

The polymer films were exceptionally tough and exhibited good thermal stability. Films exhibited conductivities of 10–3 S cm–1 after heating in air to 310 °C and 10–2 S cm–1 after heating in argon to 550 °C.

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Article information

DOI
https://doi.org/10.1039/JM9910100103
Article type
Paper

J. Mater. Chem., 1991,1, 103-104

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Thermal and electrical conduction studies on polypyrrole tetracyanoplatinate

S. Edge, A. E. Underhill, P. Kathirgamanathan, P. O'Connor and A. J. Dent, J. Mater. Chem., 1991, 1, 103 DOI: 10.1039/JM9910100103

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