Faraday communications. Microwave spectroscopy of pyrolytically produced, rapidly isolated transient molecules
Abstract
31 P Spin–rotation hyperfine splitting has been observed in the 101â†�000 transitions of CH2P35Cl and CH2P37Cl by pulsed-nozzle, FT microwave spectroscopy. The transient molecules CH2PCl were produced by using a pyrolysis nozzle and then isolated on the ca. 10 µs timescale.