The structure of Li3Cu2O4, synthesised under high oxygen pressure, has been determined from powder X-ray data. The compound contains chains of edge-sharing CuO4 square planes co-ordinated to lithium in both tetrahedral and square-planar sites.
M. T. Weller, D. R. Lines and D. B. Currie, J. Chem. Soc., Dalton Trans., 1991, 3137 DOI: 10.1039/DT9910003137
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