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Issue 3, 1991
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Differentiation of isomeric coordination geometries by metal valence: a structural study of its origin in [Os(EtSCS2)2(PPh3)2]z(z= 0 and 1+)

Abstract

In the title complexes OsII and OsIII display strong preferences for cis- and trans-S4P2 geometries respectively; structural parameters of the cis-OsII, trans-OsII and trans-OsIII isomers have revealed that back-bonding and steric crowding within the Os(PPh3)2 fragment are the primary controlling factors.

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Article information


J. Chem. Soc., Chem. Commun., 1991, 139-141
Article type
Paper

Differentiation of isomeric coordination geometries by metal valence: a structural study of its origin in [Os(EtSCS2)2(PPh3)2]z(z= 0 and 1+)

A. Pramanik, N. Bag, D. Ray, G. K. Lahiri and A. Chakravorty, J. Chem. Soc., Chem. Commun., 1991, 139
DOI: 10.1039/C39910000139

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