The first stable aldehyde and ketone complexes of zinc: the structure of [Zn(SeC6H2But3)2(p-O
CHC6H4OMe)]2
Abstract
The reaction of Zn(EC6H2But3)2(E = S or Se) with organic carbonyl compounds gives the first isolable aldehyde and ketone complexes of zinc as models for transient metal-substrate complexes in metalloenzymes such as liver alcohol dehydrogenase.
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CHC6H4OMe)]2