The formation and characterization of gas-phase ion complexes of a perfluorinated cryptand, perfluoro 4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane, with F– and O2 demonstrates that intrinsic host–guest chemistry may be examined in the solvent-free environment of a mass spectrometer.
J. Brodbelt, S. Maleknia, R. Lagow and T. Y. Lin, J. Chem. Soc., Chem. Commun., 1991, 1705 DOI: 10.1039/C39910001705
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