The treatment of Ni/SiO2 with tartaric acid induces enantioselectivity and corrosively leaches nickel tartrate, which is also optically selective, into solution; in contrast to reports in the literature nickel metal is not essential for asymmetric activity.
M. A. Keane and G. Webb, J. Chem. Soc., Chem. Commun., 1991, 1619 DOI: 10.1039/C39910001619
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