The powerful π-electron donor, tetrathiafulvalene, forms a strong green-coloured 1 : 1 complex with the π-electron accepting tetracationic cyclophane, cyclobis(Paraquat-p-phenylene), in both the solid and solution states as demonstrated by X-ray crystallography and spectroscopy (NMR and UV–VIS), respectively.
D. Philp, A. M. Z. Slawin, N. Spencer, J. F. Stoddart and D. J. Williams, J. Chem. Soc., Chem. Commun., 1991, 1584 DOI: 10.1039/C39910001584
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