Incorporation of [4′-2H], [2-13C]tryptophan, and [methyl-2H3]brassinin 1 into spirobrassinin 3 by UV-irradiated turnip tissue indicates that spirobrassinin 3 is formed via brassmin 1, which is biosynthesized from tryptophan by a pathway involving a molecular rearrangement and possible formation of indol-3-ylmethyl isothiocyanate 6a.
K. Monde and M. Takasugi, J. Chem. Soc., Chem. Commun., 1991, 1582 DOI: 10.1039/C39910001582
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