The orthoester Claisen rearrangement is used as a key reaction in the facile conversion of an acetaldehyde moiety stereospecifically into the (E)-4-methylhex-4-enoic acid side-chain of mycophenolic acid.
J. W. Patterson and G. T. Huang, J. Chem. Soc., Chem. Commun., 1991, 1579 DOI: 10.1039/C39910001579
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