Issue 21, 1991

Formation and structure of a quadruply-iodo-bridged complex of dimolybdenum(III,IV), [(Cp*Mo)2(µ-l)4]l3(Cp*=η5-C5Me5) and its reversible oxidation and reduction

Abstract

The mixed-valence quadruply-iodo-bridged [(Cp*Mo)2(µ-l)4]l3 has been crystallographically characterized; its cyclic voltammogram shows reversible oxidation and reduction processes and suggests that the [(Cp*Mo)2(µ-l)4]n+(n= 0,1,2) series of complexes is isostructural.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 1518-1520

Formation and structure of a quadruply-iodo-bridged complex of dimolybdenum(III,IV), [(Cp*Mo)2(µ-l)4]l3(Cp*=η5-C5Me5) and its reversible oxidation and reduction

R. Poli, J. C. Gordon, J. U. Desai and A. L. Rheingold, J. Chem. Soc., Chem. Commun., 1991, 1518 DOI: 10.1039/C39910001518

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