The vapours of titanium or vanadium react with 1,4-di-tert-butylbuta-1,3-diene to afford the novel, homoleptic diene complexes [M(η-1,4-But2C4H4)2], M = Ti, V.
F. G. N. Cloke and A. McCamley, J. Chem. Soc., Chem. Commun., 1991, 1470 DOI: 10.1039/C39910001470
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