Tellurium tetrafluoride reacts at 195 K in CD2Cl2 with Rh(CO)X(PEt3)2[X = Cl, Br, NCS, NCO] to give the novel complexes [Rh(CO)X(PEt3)2(TeF3)+][TeF5–], which have been characterised by 19F, 31P and 13C NMR spectroscopy; for X = Cl, Br and NCS the complexes are stable at ambient temperature but for X = NCO decomposition occurs at 215 K.
E. A. V. Ebsworth, J. H. Holloway and P. G. Watson, J. Chem. Soc., Chem. Commun., 1991, 1443 DOI: 10.1039/C39910001443
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