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Issue 19, 1991
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Reactions of the terminal rhenium acetylide complex Re(η5-C5H5)(NO)(PPh3)(C[triple bond, length half m-dash]CH) and butyllithium; generation, alkylation and stannylation of lithiocarbide complexes of the formula Re(η5-C5H4)(NO)(PPh3)(C[triple bond, length half m-dash]CLi)(X = H, Li)

Abstract

The title reaction gives, depending upon stoichiometry and conditions, Re(η5-C5H5)(NO)(PPh3)(C[triple bond, length half m-dash]CLi) and Re(η5-C5H4Li)(NO)(PPh3)(C[triple bond, length half m-dash]CLi); the first transition metal–alkali metal carbide complexes which are in turn derivatized by carbon and metal electrophiles.

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Article type: Paper
DOI: 10.1039/C39910001360
J. Chem. Soc., Chem. Commun., 1991, 1360-1362

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    Reactions of the terminal rhenium acetylide complex Re(η5-C5H5)(NO)(PPh3)(C[triple bond, length half m-dash]CH) and butyllithium; generation, alkylation and stannylation of lithiocarbide complexes of the formula Re(η5-C5H4)(NO)(PPh3)(C[triple bond, length half m-dash]CLi)(X = H, Li)

    J. A. Ramsden, F. Agbossou, D. R. Senn and J. A. Gladysz, J. Chem. Soc., Chem. Commun., 1991, 1360
    DOI: 10.1039/C39910001360

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