Issue 18, 1991

Isolation of the first gallium hydrosulphido complex and its facile conversion to a Ga4S4 cubane: X-ray structures of [(But)2Ga(µ-SH)]2 and [(ButGaS]4

Abstract

The reaction of (But)3Ga with an excess of H2S in pentane at ambient temperature results in the formation of the hydrosulphido bridged dimer [(But)2Ga(µ-SH)]2, 1, which upon mild thermolysis is converted to the cubic tetramer [(But)GaS]42. Compounds 1 and 2 have been characterized by IR, NMR and mass spectroscopy and their molecular structures have been determined by X-ray crystallography.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 1315-1317

Isolation of the first gallium hydrosulphido complex and its facile conversion to a Ga4S4 cubane: X-ray structures of [(But)2Ga(µ-SH)]2 and [(ButGaS]4

M. B. Power and A. R. Barron, J. Chem. Soc., Chem. Commun., 1991, 1315 DOI: 10.1039/C39910001315

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