γ-Dibenzylamino enals 3a with the E-configuration derived from amino acids 1 react diastereoselectively with cuprates in an unexpected 1,2-manner, while the analogues 3b with the Z-configuration undergo diastereoselective additions with organolithium reagents.
M. T. Reetz, F. Wang and K. Harms, J. Chem. Soc., Chem. Commun., 1991, 1309 DOI: 10.1039/C39910001309
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