Protonation of 2,6-diamidopyridine with diaryl phosphates leads to a conformational change in the pyridine from inwardly to outwardly directed amide-NH groups and a resultant self-assembly of the anion and cation into an alternating cocrystal with a novel hydrogen bonding motif.
S. J. Geib, S. C. Hirst, C. Vicent and A. D. Hamilton, J. Chem. Soc., Chem. Commun., 1991, 1283 DOI: 10.1039/C39910001283
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