Reaction of Group 6 metallacarbynes with cyclopalladated dimers leads to C–C bond formation, for which reaction an intermediate has been characterized by X-ray diffraction methods; both structural data and extended Hückel calculations suggest the metallacarbyne to be η1-bonded to Pd via the carbyne carbon atom.
P. F. Engel, M. Pfeffer, J. Fischer and A. Dedieu, J. Chem. Soc., Chem. Commun., 1991, 1274 DOI: 10.1039/C39910001274
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