Two-electron donor ligands L enter trans(and not cis as in other manganese examples) to the acyl group in the reaction of fac-[Mn(CO)3(bipy)(Me)]1 with L to give cis,trans-[Mn(CO)2(L)(bipy)(COMe)]2; the reaction of 1 with *CO (CO 99% enriched in 13C) gives cis,trans-[Mn(CO)2(*CO)(bipy)(COMe)]4, ruling out the formation of the possible intermediate cis,cis-[Mn(CO)2(L)(bipy)(COMe)]3.
F. J. G. Alonso, A. Llamazares, V. Riera, M. Vivanco, M. R. Díaz and S. G. Granda, J. Chem. Soc., Chem. Commun., 1991, 1058 DOI: 10.1039/C39910001058
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