In liquid-phase heterogeneous catalytic-transfer reduction, the concentration of hydrogen donor is of extreme importance, being able to suppress reaction entirely if it is not kept very low relative to the concentration of the reducible substrate; biphasic solvent systems provide a simple means of exercising the required control.
A. F. Brigas and R. A. W. Johnstone, J. Chem. Soc., Chem. Commun., 1991, 1041 DOI: 10.1039/C39910001041
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