At high buffer concentrations the enolisation of aldehydes is markedly catalysed simultaneously by acidic and basic species; the magnitude of the ‘third-order term’ can be related directly to the importance of the individual acid and base catalysed terms.
A. F. Hegarty and J. Dowling, J. Chem. Soc., Chem. Commun., 1991, 996 DOI: 10.1039/C39910000996
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