Ethane reacts with both cobalt(III) and O2–cobalt(II) in trifluoroacetic acid solution to form ethyl trifluoroacetate and 1,2-bistrifluoroacetoxyethane in successive reactions, along with the products of C–C bond cleavage; propane undergoes similar oxidative reactions.
I. P. Stolarov, M. N. Vargaftik, D. I. Shishkin and I. I. Moiseev, J. Chem. Soc., Chem. Commun., 1991, 938 DOI: 10.1039/C39910000938
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