Issue 13, 1991

Stereoselective synthesis of highly labile (Z)-β-alkylvinyl(phenyl)iodonium perchlorates

Abstract

Labile (Z)-vinyl(phenyl)iodonium perchlorates 2(X = ClO4) were synthesised from (Z)-vinylsilanes 1 by the reaction with (diacetoxyiodo)benzene in the presence of BF3–Et2O in dichloromethane, followed by quenching with aqueous potassium perchlorate solution.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 869-870

Stereoselective synthesis of highly labile (Z)-β-alkylvinyl(phenyl)iodonium perchlorates

M. Ochiai, K. Oshima and Y. Masaki, J. Chem. Soc., Chem. Commun., 1991, 869 DOI: 10.1039/C39910000869

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