Electron transfer between dioxiranes 1 and nitroxide 2 affords the dioxirane radical anion–oxoammonium cation pair, which generates methyl radicals that are trapped by the nitroxide.
W. Adam, S. E. Bottle and R. Mello, J. Chem. Soc., Chem. Commun., 1991, 771 DOI: 10.1039/C39910000771
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