Issue 10, 1991

Novel bonding geometry and valence tautomerism of 4-(N,N-dimethyldithiocarbamato)-2-dimethyliminio-1,3-dithietane tetraphenylborate, [Me2NCS2·CH·S2CNMe2]+Ph4B

Abstract

A ring-opening/ring-closing tautomerism in solution of the title compound is deduced from the temperature dependence of the 1H NMR spectra; the molecular structure found by X-ray crystal analysis is favourably oriented for this tautomerism.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 719-721

Novel bonding geometry and valence tautomerism of 4-(N,N-dimethyldithiocarbamato)-2-dimethyliminio-1,3-dithietane tetraphenylborate, [Me2NCS2·CH·S2CNMe2]+Ph4B

R. R. Schumaker, M. Inoue, M. B. Inoue, M. A. Bruck and Q. Fernando, J. Chem. Soc., Chem. Commun., 1991, 719 DOI: 10.1039/C39910000719

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