Novel organometallic reagents, such as the stable cobalt and molybdenum carbonyl complexes of hex-4-ynoic acid N-hydroxysuccinimide ester which are detectable at very low concentrations by Fourier transform infrared spectroscopy, couple with amine residues of peptides under mild conditions and provide a non-radio isotopic alternative for the widely used radioactive Bolton–Hunter tracer.
M. Savignac, A. Sasaki, P. Potier and G. Jaouen, J. Chem. Soc., Chem. Commun., 1991, 615 DOI: 10.1039/C39910000615
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