The stereoselective synthesis of 2,9,10-trioxatricyclo[4.3.1.0]decane analogues of resiniferatoxin
Abstract
Structurally simplified analogues of the diterpene resiniferatoxin possessing a 2,9,10-trioxatricyclo[4.3.1.0]decane system are synthesised stereoselectively from cyclohexa-1,3-diene.