In the presence of a small amount of LiBH4 mono-, di-, tri- and tetra-substituted ethenes were hydroborated almost quantitatively with 1,3,2-benzodioxaborole (catecholborane) under very mild conditions.
A. Arase, Y. Nunokawa, Y. Masuda and M. Hoshi, J. Chem. Soc., Chem. Commun., 1991, 205 DOI: 10.1039/C39910000205
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